Soluções Da Calibração com Padrão Interno
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CALIBRAÇÃO (g) - DIAN 18/05/15 Amostra etOH Acetaldeído Éter Butanol Isopropanol 1 0.5242 0 0 0 0.509 1B 1.0224 0 0 0 1.0103 2 0 0.518 0 0 0.5267 2B 1.462 0 0 1.447 2C 0 2.07 0 0 2.03 3 0 0 0.5876 0 0.5266 3B 0 0 2.024 0 2.018 4 0 0 0 0.5297 0.5548 5 1.27 0.16 0.143 0.1284 2.0776 6 0.2558 1.2599 0.2511 0.2524 2.0047 7 0.2687 0.2353 1.2142 0.2598 2.006 7B 0.2595 0.27 1.27 0.2624 1.9906 8 0.3341 0.3489 0.3408 1.5605 2.5211 9 0.643 0.632 0.67 0.634 2.493 CALIBRAÇÃO (g) - DIAN 18/05/15 Amostra etOH Acetaldeído Éter Butanol Isopropanol 1 50.74% 0.00% 0.00% 0.00% 49.26% 1B 50.30% 0.00% 0.00% 0.00% 49.70% 2 0.00% 49.58% 0.00% 0.00% 50.42% 2B 0.00% 50.26% 0.00% 0.00% 49.74% 2C 0.00% 50.49% 0.00% 0.00% 49.51% 3 0.00% 0.00% 52.74% 0.00% 47.26% 3B 0.00% 0.00% 50.07% 0.00% 49.93% 4 0.00% 0.00% 0.00% 48.84% 51.16% 5 33.61% 4.23% 3.78% 3.40% 54.98% 6 6.36% 31.31% 6.24% 6.27% 49.82% 7 6.74% 5.91% 30.48% 6.52% 50.35% 7B 6.40% 6.66% 31.34% 6.48% 49.12% 8 6.54% 6.83% 6.68% 30.57% 49.38% 9 12.68% 12.46% 13.21% 12.50% 49.15%
description
Arquivo excel com dados experimentais de uma prática com GC-FID de uma curva de calibração com adição de padrão interno
Transcript of Soluções Da Calibração com Padrão Interno
MassasCALIBRAO (g) - DIAN 18/05/15AmostraetOHAcetaldedoterButanolIsopropanolSOMA10.52420000.5091.03321B1.02240001.01032.0327200.518000.52671.04472B1.462001.4472.9092C02.07002.034.13000.587600.52661.11423B002.02402.0184.04240000.52970.55481.084551.270.160.1430.12842.07763.77960.25581.25990.25110.25242.00474.023970.26870.23531.21420.25982.0063.9847B0.25950.271.270.26241.99064.052580.33410.34890.34081.56052.52115.105490.6430.6320.670.6342.4935.072CALIBRAO (g) - DIAN 18/05/15AmostraetOHAcetaldedoterButanolIsopropanolSOMA150.74%0.00%0.00%0.00%49.26%100.00%1B50.30%0.00%0.00%0.00%49.70%100.00%20.00%49.58%0.00%0.00%50.42%100.00%2B0.00%50.26%0.00%0.00%49.74%100.00%2C0.00%50.49%0.00%0.00%49.51%100.00%30.00%0.00%52.74%0.00%47.26%100.00%3B0.00%0.00%50.07%0.00%49.93%100.00%40.00%0.00%0.00%48.84%51.16%100.00%533.61%4.23%3.78%3.40%54.98%100.00%66.36%31.31%6.24%6.27%49.82%100.00%76.74%5.91%30.48%6.52%50.35%100.00%7B6.40%6.66%31.34%6.48%49.12%100.00%86.54%6.83%6.68%30.57%49.38%100.00%912.68%12.46%13.21%12.50%49.15%100.00%
InjeesreaAmostraCALIBRAOAcetaldedoetOHIsopropanolterButanol1CALIBRAO 1958879416.3740851.82597307664259377.3782270.534970399CALIBRAO 2057831693.61.27%63153079.71.23%2CALIBRAO 751922961.89901233.2172118376890245.614029861.279724845332670.783515723.651922961.837920503.50.6647002848CALIBRAO 837920503.522.04%57049025.520.95%42925327.48193349976890245.657049025.50.67528672063CALIBRAO 9630904164685016.3060818151846574.76208943.21312093CALIBRAO 1069716029.67.06%60627346.411.04%4CALIBRAO 2866773325.24474340.4167203494379245.52258804.95350337CALIBRAO 1273100998.16.40%91184812.92.43%5CALIBRAO 133778662204418.70145474741369809.32669127.5634960874838779.95041818.993755994142499.6319921.6243130885121091.9287413.450708209CALIBRAO 144067753.75.21%45144525.76.17%81968988.76.43%4594937.17.32%5527555.95.40%6CALIBRAO 1532928638.11679930.07789678571395.631652.079424896474097205.72178292.149051879590806.3883447.89870597410069755.11005705.10553821CALIBRAO 1630552858.25.29%8526632.80.37%71016635.43.00%8341422.39.85%11492036.99.33%7CALIBRAO 175819525.8871771.3030068868593091272746.6684590765742719.111435468.468328548361700.68137219.233486588792636.71581717.047209215819525.8685930965742719.148361700.68792636.7CALIBRAO 21458665516.75%5059373.421.36%49570524.519.83%36853934.819.10%655575120.61%45866555059373.449570524.536853934.865557518CALIBRAO 234938401.1392091.8415387917123639.8222353.33358869465533543.62069164.359511368188143.5149599.1168724154133213.12223975.34833586CALIBRAO 245492902.77.52%6809184.73.19%62607303.33.23%7976578.41.85%509880374.23%9CALIBRAO 258907673.9275949.9062822914914116.8219095.33909437765835572.9999966.15619141816334710.1316991.58594388520531085.3372356.703407907CALIBRAO 2692979263.03%15223964.41.45%67249738.61.50%16783003.91.91%21057677.21.79%Razo (Componente / Isopropanol)AmostraCALIBRAOAcetaldedoetOHterButanol1CALIBRAO 190.91627741780.0003812166CALIBRAO 200.91573829610.04%2CALIBRAO 70.67528672060.0074857405CALIBRAO 80.66470028481.12%3CALIBRAO 90.82178210240.0338355566CALIBRAO 100.86963280544.00%4CALIBRAO 111.41342737110.1174123526CALIBRAO 121.24738122978.83%5CALIBRAO 130.05049069490.00061177090.55278572630.00143856860.05535231340.00049830160.06842831890.0007025797CALIBRAO 140.04962552011.22%0.55075128310.26%0.05605701830.89%0.06743472121.03%6CALIBRAO 150.44439783910.01002443650.11567771710.00310248130.12943546530.00846984140.13589925560.0183299783CALIBRAO 160.43022114512.29%0.12006528832.63%0.11745730076.86%0.161821759612.31%7CALIBRAO 170.08851970040.00283420320.1043356450.00160619020.73562063240.00554658870.1337431250.0010550979CALIBRAO 210.09252786913.13%0.1020641491.56%0.74346469340.75%0.13225099120.79%8CALIBRAO 230.07535684520.00875325260.10870219140.00004103940.12494583770.00173996250.82603824130.0082221471CALIBRAO 240.087735813710.73%0.10876022990.04%0.12740651621.38%0.81441036931.00%9CALIBRAO 250.13530183620.00209149730.22653583990.00011052580.24811373820.00102433480.3118539780.0008998292CALIBRAO 260.13825966011.53%0.22637953270.05%0.24956236630.41%0.31312652860.29%
CurvasAcetaldedoEtanolterButanolConcentraoRazo Conc.isopropanol*Comp / IsopropanolConcentraoRazo Conc.isopropanol*Comp / IsopropanolConcentraoRazo Conc.isopropanol*Comp / IsopropanolConcentraoRazo Conc.isopropanol*Comp / Isopropanol
6.68%0.04483213926.54%0.05369261086.83%0.06230711796.52%0.09197180112.46%0.067230758112.68%0.111308953513.21%0.122309397512.50%0.153595859931.31%0.217866830433.61%0.303348569831.34%0.363265545930.57%0.405035353950.49%0.331728490450.30%0.455277580552.74%0.5948.84%0.6805977924
DadosRazo (Componente / Isopropanol)AmostraCALIBRAOAcetaldedoetOHterButanol1CALIBRAO 190.91627741780.916007857CALIBRAO 200.91573829610.04%2CALIBRAO 70.67528672060.6699935027CALIBRAO 80.66470028481.12%3CALIBRAO 90.82178210240.8457074539CALIBRAO 100.86963280544.00%CALIBRAO (g) - DIAN 18/05/154CALIBRAO 111.41342737111.3304043004AmostraetOHAcetaldedoterButanolIsopropanolCALIBRAO 121.24738122978.83%150.30%0.00%0.00%0.00%49.70%5CALIBRAO 130.05049069490.05005810750.55278572630.55176850470.05535231340.05570466590.06842831890.067931520120.00%50.49%0.00%0.00%49.51%CALIBRAO 140.04962552011.22%0.55075128310.26%0.05605701830.89%0.06743472121.03%30.00%0.00%52.74%0.00%47.26%6CALIBRAO 150.44439783910.43730949210.11567771710.11787150270.12943546530.1234463830.13589925560.148860507640.00%0.00%0.00%48.84%51.16%CALIBRAO 160.43022114512.29%0.12006528832.63%0.11745730076.86%0.161821759612.31%533.61%4.23%3.78%3.40%54.98%7CALIBRAO 170.08851970040.09052378470.1043356450.1031998970.73562063240.73954266290.1337431250.132997058166.36%31.31%6.24%6.27%49.82%CALIBRAO 210.09252786913.13%0.1020641491.56%0.74346469340.75%0.13225099120.79%76.40%6.66%31.34%6.48%49.12%8CALIBRAO 230.07535684520.08154632950.10870219140.10873121070.12494583770.12617617690.82603824130.820224305386.54%6.68%6.83%30.57%49.38%CALIBRAO 240.087735813710.73%0.10876022990.04%0.12740651621.38%0.81441036931.00%912.68%12.46%13.21%12.50%49.15%9CALIBRAO 250.13530183620.13678074810.22653583990.22645768630.24811373820.24883805230.3118539780.3124902533CALIBRAO 260.13825966011.53%0.22637953270.05%0.24956236630.41%0.31312652860.29%AcetaldedoEtanolterButanolAcetaldedoEtanolterButanol6.68%0.08154632956.54%0.10873121076.83%0.12617617696.52%0.1826598486.68%0.04026843176.54%0.05369261086.83%0.06230711796.52%0.089723058212.46%0.136780748112.68%0.226457686313.21%0.248838052312.50%0.312490253312.46%0.067230758112.68%0.111308953513.21%0.122309397512.50%0.153595859931.31%0.437309492133.61%0.551768504731.34%0.739542662930.57%0.820224305331.31%0.217866830433.61%0.303348569831.34%0.363265545930.57%0.405035353950.49%0.669993502750.30%0.91600785752.74%0.845707453948.84%1.330404300450.49%0.331728490450.30%0.455277580552.74%0.399703415248.84%0.6805977924
Dados limposConcentraesreasRazoFator de RespostaAmostraAcetaldeidoEtanolIsopropanolterButanolAcetaldeidoEtanolIsopropanolterButanolAcetaldeidoEtanolIsopropanolterButanolAcetaldeidoEtanolIsopropanolterButanolAcetaldeidoEtanolIsopropanolterButanolAmostra 10.00%50.74%49.26%0.00%0.00%069651120.471865334.50000.9691893997100ERROR:#DIV/0!0.94108623511ERROR:#DIV/0!ERROR:#DIV/0!0ERROR:#DIV/0!0.96778818850.20%10.00%0ERROR:#DIV/0!0ERROR:#DIV/0!Amostra 10.00%50.74%49.26%0.00%0.00%057452801.459451133.70000.9663869774100ERROR:#DIV/0!0.93836507341ERROR:#DIV/0!ERROR:#DIV/0!Amostra 1B0.00%50.30%49.70%0.00%0.00%058879416.364259377.30000.9162774178100ERROR:#DIV/0!0.90543336771ERROR:#DIV/0!ERROR:#DIV/0!0ERROR:#DIV/0!0.9160078570.04%10.00%0ERROR:#DIV/0!0ERROR:#DIV/0!Amostra 1B0.00%50.30%49.70%0.00%0.00%057831693.663153079.70000.9157382961100ERROR:#DIV/0!0.90490062651ERROR:#DIV/0!ERROR:#DIV/0!Amostra 249.58%0.00%50.42%0.00%0.00%41820115.8076322819.5000.547937249601000.5571400567ERROR:#DIV/0!1ERROR:#DIV/0!ERROR:#DIV/0!0.470887587323.14%0ERROR:#DIV/0!10.00%0ERROR:#DIV/0!0ERROR:#DIV/0!Amostra 249.58%0.00%50.42%0.00%0.00%38619798.8098060131.7000.393837925101000.4004525775ERROR:#DIV/0!1ERROR:#DIV/0!ERROR:#DIV/0!Amostra 2B50.26%0.00%49.74%0.00%0.00%45733710.8083606792.1000.54700951501000.5413972423ERROR:#DIV/0!1ERROR:#DIV/0!ERROR:#DIV/0!0.53525899463.10%0ERROR:#DIV/0!10.00%0ERROR:#DIV/0!0ERROR:#DIV/0!Amostra 2B50.26%0.00%49.74%0.00%0.00%43299523082710261.9000.523508474101000.5181373201ERROR:#DIV/0!1ERROR:#DIV/0!ERROR:#DIV/0!Amostra 2C50.49%0.00%49.51%0.00%0.00%51922961.8076890245.6000.675286720601000.6622377019ERROR:#DIV/0!1ERROR:#DIV/0!ERROR:#DIV/0!0.66999350271.12%0ERROR:#DIV/0!10.00%0ERROR:#DIV/0!0ERROR:#DIV/0!Amostra 2C50.49%0.00%49.51%0.00%0.00%37920503.5057049025.5000.664700284801000.6518558349ERROR:#DIV/0!1ERROR:#DIV/0!ERROR:#DIV/0!Amostra 30.00%0.00%47.26%52.74%0.00%0071511056.987871807.100011.22878630120ERROR:#DIV/0!ERROR:#DIV/0!11.1012233938ERROR:#DIV/0!0ERROR:#DIV/0!0ERROR:#DIV/0!10.00%1.047914646824.41%0ERROR:#DIV/0!Amostra 30.00%0.00%47.26%52.74%0.00%0069924267.860627346.400010.86704299250ERROR:#DIV/0!ERROR:#DIV/0!10.7770334238ERROR:#DIV/0!Amostra 3B0.00%0.00%49.93%50.07%0.00%0073515145.387768551.900011.19388394790ERROR:#DIV/0!ERROR:#DIV/0!11.1903447662ERROR:#DIV/0!0ERROR:#DIV/0!0ERROR:#DIV/0!10.00%1.19336294350.06%0ERROR:#DIV/0!Amostra 3B0.00%0.00%49.93%50.07%0.00%0071329985.985085398.700011.19284193910ERROR:#DIV/0!ERROR:#DIV/0!11.1893058464ERROR:#DIV/0!Amostra 40.00%0.00%51.16%0.00%48.84%0070458877.5094269022.300101.337929664ERROR:#DIV/0!ERROR:#DIV/0!1ERROR:#DIV/0!1.40132787920ERROR:#DIV/0!0ERROR:#DIV/0!10.00%0ERROR:#DIV/0!1.29265544684.95%Amostra 40.00%0.00%51.16%0.00%48.84%0073100998.1091184812.900101.2473812297ERROR:#DIV/0!ERROR:#DIV/0!1ERROR:#DIV/0!1.306488779Amostra 54.23%33.61%54.98%3.78%3.40%377866241716339.975388012.74142499.65280105.20.05012284930.553355081310.05494904890.07003905540.65084519820.905236627610.7983366721.13327991860.05006600810.16%0.55253191880.21%10.00%0.05553497781.49%0.06879550552.56%Amostra 54.23%33.61%54.98%3.78%3.40%4092086.845144525.781826734.14592190.55527555.90.05000916690.551708756310.05612090660.06755195550.64936903180.902543395310.81536220631.0930369372Amostra 631.31%6.36%49.82%6.24%6.27%32928638.18718361.674703279.39590806.310128960.50.44079240440.116706544610.12838534520.13558923510.70137037310.914627091611.02498646561.07692448340.43550677471.72%0.11838591642.01%10.00%0.1229213236.29%0.14583262969.93%Amostra 631.31%6.36%49.82%6.24%6.27%30552858.28526632.871016635.48341422.311083994.10.43022114510.120065288310.11745730070.15607602410.6845498290.940949504910.93774054461.2396418604Amostra 75.91%6.74%50.35%30.48%6.52%5957899.68806799.37034049349386421.711472087.30.08470085080.125202410810.70210514020.16309364370.72209905070.934707986811.15995957111.25929888060.08251972643.74%0.1255276020.37%10.00%0.68927871482.63%0.16547732282.04%Amostra 75.91%6.74%50.35%30.48%6.52%48204277551341.360001380.24058807110071891.80.08033860190.125852793310.67645228930.1678610020.68490962810.939563466211.11757806991.2961091992Amostra 7B6.66%6.40%49.12%31.34%6.48%5819525.8685930965742719.148361700.68792636.70.08851970040.10433564510.73562063240.1337431250.65261968770.800348882111.15301293771.01459247210.09052378473.13%0.1031998971.56%10.00%0.73954266290.75%0.13299705810.79%Amostra 7B6.66%6.40%49.12%31.34%6.48%45866555059373.449570524.536853934.865557510.09252786910.10206414910.74346469340.13225099120.6821702820.782924451111.16530773131.0032729539Amostra 86.83%6.54%49.38%6.68%30.57%4938401.17112074.365533543.68172538.154133213.10.07535684520.108525709310.12470770920.82603824130.54451746180.818928960310.92253698871.33452419740.081546329510.73%0.10864296960.15%10.00%0.12605711271.51%0.82102727150.86%Amostra 86.83%6.54%49.38%6.68%30.57%5492902.76809184.762607303.37976578.451088580.10.08773581370.108760229910.12740651620.81601630170.63396606470.820698639910.94250166641.3183330332Amostra 912.46%12.68%49.15%13.21%12.50%8907673.914914116.865835572.916334710.120531085.30.13530183620.226535839910.24811373820.3118539780.53371436330.878310806810.92320529761.22626493230.13678074811.53%0.22645768630.05%10.00%0.24883805230.41%0.31249025330.29%Amostra 912.46%12.68%49.15%13.21%12.50%929792615223964.467249738.616783003.921057677.20.13825966010.226379532710.24956236630.31312652860.54538185540.877704782410.92859549141.23126882640.64282902590.88049132781.01919816111.20959745389.31%6.05%13.79%10.33%Terico-0.460.530.550.66(Referencia com PI de F=1)Terico(Referecia PI Isopropanol)-0.867924528311.03773584911.2452830189
Cruvas 2ConcentraesRazoAcetaldeidoEtanolIsopropanolterButanolAcetaldeidoEtanolIsopropanolterButanol0.00%50.30%49.70%0.00%0.00%00.91627741781000.00%50.30%49.70%0.00%0.00%00.915738296110050.49%0.00%49.51%0.00%0.00%0.6752867206010050.49%0.00%49.51%0.00%0.00%0.664700284801000.00%0.00%49.93%50.07%0.00%0011.193883947900.00%0.00%49.93%50.07%0.00%0011.192841939100.00%0.00%51.16%0.00%48.84%00101.3379296640.00%0.00%51.16%0.00%48.84%00101.24738122974.23%33.61%54.98%3.78%3.40%0.05012284930.553355081310.05494904890.07003905544.23%33.61%54.98%3.78%3.40%0.05000916690.551708756310.05612090660.067551955531.31%6.36%49.82%6.24%6.27%0.44079240440.116706544610.12838534520.135589235131.31%6.36%49.82%6.24%6.27%0.43022114510.120065288310.11745730070.15607602415.91%6.74%50.35%30.48%6.52%0.08470085080.125202410810.70210514020.16309364375.91%6.74%50.35%30.48%6.52%0.08033860190.125852793310.67645228930.1678610026.66%6.40%49.12%31.34%6.48%0.08851970040.10433564510.73562063240.1337431256.66%6.40%49.12%31.34%6.48%0.09252786910.10206414910.74346469340.13225099126.83%6.54%49.38%6.68%30.57%0.07535684520.108525709310.12470770920.82603824136.83%6.54%49.38%6.68%30.57%0.08773581370.108760229910.12740651620.816016301712.46%12.68%49.15%13.21%12.50%0.13530183620.226535839910.24811373820.31185397812.46%12.68%49.15%13.21%12.50%0.13825966010.226379532710.24956236630.3131265286
